A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination.

نویسندگان

  • Zhuo Chai
  • Dezhi Hua
  • Kui Li
  • Jiang Chu
  • Gaosheng Yang
چکیده

A new chiral silicon-linked tridentate amido-indenyl ligand was developed from indene and enantiopure 1,2-cyclohexanediamine. Its yttrium complex was synthesized, characterized and applied to efficiently catalyze the intramolecular hydroamination of non-activated olefins with up to 97% ee.

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عنوان ژورنال:
  • Chemical communications

دوره 50 2  شماره 

صفحات  -

تاریخ انتشار 2014